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Chemical Product CAS:16853-85-3Lithium aluminum hydride

CAS:16853-85-3
Lithium aluminum hydride

  • CAS No:

    16853-85-3
  • Name:

    Lithium aluminum hydride
  • Molecular Formula:

    LiAlH4
  • Molecular Weight:

    37.95
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Lithium aluminum hydride ( CASNO:16853-85-3 )

Identification and Related Records
Name:
Lithium aluminum hydride
CAS Registry number:
16853-85-3
Synonyms:
LAH
Lithium tetrahydridoaluminate
lithiumtetrahydroaluminate
Lithium aluminium hydride
Aluminum lithium hydride
Aluminium lithium hydride 95+ %
LITHIUM ALUMINUM HYDRIDE,PELLETS
EINECS(EC#):
240-877-9
Molecular Formula:
LiAlH4
Molecular Weight:
37.95
Inchi:
InChI=1/Al.Li.4H/q-1;+1;;;;/rAlH4.Li/h1H4;/q-1;+1
InChIKey:
OCZDCIYGECBNKL-UHFFFAOYSA-N
Canonical SMILES:
CN(C)C=C(C#N)C#N
Chemical and Physical Properties
Appearance:
white crystalline powder
Density:
0.917
Melting Point:
125℃
Boiling Point:
0°C
Flash Point:
-17℃
Water:
Reacts
Solubilities:
Reacts
Stability:
Stable. Reacts violently with water, liberating hydrogen. Incompatible with strong oxidizing agents, alcohols, acids.
Storage temp:
2-8°C
Computed Properties:
Molecular Weight:121.13988 [g/mol]
Molecular Formula:C6H7N3
XLogP3-AA:0.3
H-Bond Donor:0
H-Bond Acceptor:3
Rotatable Bond Count:1
Exact Mass:121.063997
MonoIsotopic Mass:121.063997
Topological Polar Surface Area:50.8
Heavy Atom Count:9
Formal Charge:0
Complexity:189
Isotope Atom Count:0
Defined Atom Stereocenter Count:0
Undefined Atom Stereocenter Count:0
Defined Bond Stereocenter Count:0
Undefined Bond Stereocenter Count:0
Covalently-Bonded Unit Count:1
Feature 3D Acceptor Count:2
Feature 3D Cation Count:1
Effective Rotor Count:1
Conformer Sampling RMSD:0.4
CID Conformer Count:2
Safety and Handling
Hazard Codes:
C:Corrosive
Risk Statements:
R11;R14/15;R34
Safety Statements:
S16;S26;S33;S36/37/39;S43;S45;S6;S7/8
HazardClass:
4.3
Safety:
Safety Information of  Lithium aluminium hydride (CAS NO.16853-85-3):
Hazard Codes: FFlammable,CCorrosive,XiIrritant,XnHarmful,F+Highly
Risk Statements:  15-34-14/15-11-36/37-19-40-10-67-66-22-12    
R15:Contact with water liberates extremely flammable gases. 
R34:Causes burns.
R14 :Reacts violently with water. 
R11:Highly flammable. 
R36/37:Irritating to eyes and respiratory system. 
R19:May form explosive peroxides. 
R40:Limited evidence of a carcinogenic effect. 
R10:Flammable. 
R67:Vapours may cause drowsiness and dizziness. 
R66:Repeated exposure may cause skin dryness or cracking. 
R22:Harmful if swallowed. 
R12:Extremely flammable.
Safety Statements: 43-7/8-6A-45-43B-36/37/39-33-26-16-24/25-27-29 
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.) 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.) 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S33:Take precautionary measures against static discharges. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S16:Keep away from sources of ignition. 
S24/25:Avoid contact with skin and eyes. 
S27:Take off immediately all contaminated clothing. 
S29:Do not empty into drains.
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 2
RTECS: BD0100000
F: 10-21
TSCA: Yes
HazardClass: 4.3
PackingGroup: I
PackingGroup:
I
Sensitive:
Air & Moisture Sensitive
Transport:
UN 1410/1411
Specification:
 Lithium aluminium hydride , its CAS NO. is 16853-85-3, the synonyms are Aluminate(1-), tetrahydro-, lithium ; Aluminate(1-), tetrahydro-, lithium, (T-4)- ; Aluminum lithium hydride ; Lithium alanate ; Lithium aluminohydride ; Lithium aluminum hydride, ethereal ;  Lithium aluminum tetrahydride ; Lithium tetrahydroaluminate .
Report:
Reported in EPA TSCA Inventory.
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